Browsing by Author "Quan, Cui"

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Access status: Open Access ,
Biomass CO2 gasification with CaO looping for syngas production in a fixed-bed reactor
(2020) Gao, Ningbo; Śliz, Maciej; Quan, Cui; Bieniek, Artur; Magdziarz, Aneta
Wydział Inżynierii Metali i Informatyki Przemysłowej
The most important challenge in solid feedstock thermal conversion methods is minimising $CO_{2}$ emissions. In this work, the gasification of pine sawdust in a mixture of $N_{2}$ and $CO_{2}$ was investigated for the reduction of $CO_{2}$ by a calcium oxide loop. The experiments were conducted at 600, 700, and 800 °C in a fixed-bed reactor. The biomass was mixed with the calcium oxide at a ratio of 1:1. The chemical composition of the syngas was analysed using gas chromatography. Moreover, the high heating values of the received gas samples were calculated, and thermogravimetric analysis and Fourier-transform infrared spectroscopy analysis were performed to investigate the absorption of $CO_{2}$ by $CaO$. The results of the gasification process showed that the syngas contained $CO$, $CH_{4}$, $CO_{2}$, $H_{2}$, $N_{2}$, and other low hydrocarbons. The most significant results were obtained for a 2:1 ratio of $N_{2}$ to $CO_{2}$ at 700 °C, and a $CO_{2}$ reduction of 25% was observed. Moreover, the catalytic properties of $CaO$ increased the concentration of $H_{2}$ in the produced syngas by up to 10%. A temperature of 800 °C was too high for the carbonation reaction of $CaO$. This study presents a possible solution for achieving negative carbon emissions.
Access status: Open Access ,
Biomass thermochemical conversion via pyrolysis with integrated CO2 capture
(2020) Sieradzka, Małgorzata; Gao, Ningbo; Quan, Cui; Mlonka-Mędrala, Agata; Magdziarz, Aneta
Wydział Inżynierii Metali i Informatyki Przemysłowej
The presented work is focused on biomass thermochemical conversion with integrated $CO_{2}$ capture. The main aim of this study was the in-depth investigation of the impact of pyrolysis temperature (500, 600 and 700 °C) and $CaO$ sorbent addition on the chemical and physical properties of obtained char and syngas. Under the effect of the pyrolysis temperature, the properties of biomass chars were gradually changed, and this was confirmed by examination using thermal analysis, scanning electron microscopy, X-ray diffraction, and porosimetry methods. The chars were characterised by a noticeable carbon content (two times at 700 °C) resulting in a lower O/C ratio. The calculated combustion indexes indicated the better combustible properties of chars. In addition, structural morphology changes were observed. However, the increasing pyrolysis temperature resulted in changes of solid products; the differences of char properties were not significant in the range of 500 to 700 °C. Syngas was analysed using a gas chromatograph. The following main components were identified: $CO$, $CO_{2}$, $CH_{4}$, $H_{2}$ and $C_{2}H_{4}$, $C_{2}H_{6}$, $C_{3}H_{6}$, $C_{3}H_{8}$. A significant impact of $CaO$ on $CO_{2}$ adsorption was found. The concentration of $CO_{2}$ in syngas decreased with increased temperature, and the highest decrease occurred in the presence of $CaO$ from above 60% to below 30% at 600 °C.